{"created":"2023-06-21T07:31:17.006301+00:00","id":2701,"links":{},"metadata":{"_buckets":{"deposit":"3318b148-991b-4c26-9205-6966030dbc81"},"_deposit":{"created_by":3,"id":"2701","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"2701"},"status":"published"},"_oai":{"id":"oai:k-kentan.repo.nii.ac.jp:00002701","sets":["10:258:261"]},"author_link":["2992","2991"],"item_3_biblio_info_12":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1954-01-20","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"53_a","bibliographicPageStart":"55_a","bibliographicVolumeNumber":"4","bibliographic_titles":[{}]}]},"item_3_description_10":{"attribute_name":"抄録(日)","attribute_value_mlt":[{"subitem_description":"キシランの化学構造に関してはエスパルトキシランの如く、末端にl-アラボ、フラノシードを附着するものもあるが、主幹はα-キシロ、ピラノーゼがC_1～C_4結合をなすものと考えられる。過沃素酸は1分子のグリコール結合に対し、当量作用し、ジアルデヒドを生成する性質があるが、これは既にα-グルコーズの如き単糖類、トレハローズの如き複糖類、澱粉、セルロ-ズの如き多糖類の酸化に応用された。著者はキシランに過沃素酸溶液を作用させ、酸化キシランを加水分解し、グリセリンアルデヒドと見做される物質を得た。これは恐らく次の反応が起るものと推定される。なお寒天に対し同じく過沃素酸酸化を行つたが、殆んど作用せず、これは主要炭水化物が1及び3の炭素位置に於て結合すること、即ちβ-ガラクトピラノーズ型であるためと考えられる。","subitem_description_type":"Other"}]},"item_3_description_15":{"attribute_name":"表示順","attribute_value_mlt":[{"subitem_description":"11","subitem_description_type":"Other"}]},"item_3_description_16":{"attribute_name":"アクセション番号","attribute_value_mlt":[{"subitem_description":"KJ00002364304","subitem_description_type":"Other"}]},"item_3_source_id_1":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00364467","subitem_source_identifier_type":"NCID"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"坂本, 清"},{"creatorName":"サカモト, キヨシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"2991","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"SAKAMOTO, Kiyoshi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"2992","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-07-25"}],"displaytype":"detail","filename":"KJ00002364304.pdf","filesize":[{"value":"108.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KJ00002364304.pdf","url":"https://k-kentan.repo.nii.ac.jp/record/2701/files/KJ00002364304.pdf"},"version_id":"d3e71953-abc7-4cf0-a101-df19b9d1c64d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"過沃素酸によるキシランの酸化について","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"過沃素酸によるキシランの酸化について"},{"subitem_title":"On the Oxidation of xylan by Periodic-acid","subitem_title_language":"en"}]},"item_type_id":"3","owner":"3","path":["261"],"pubdate":{"attribute_name":"公開日","attribute_value":"2016-07-25"},"publish_date":"2016-07-25","publish_status":"0","recid":"2701","relation_version_is_last":true,"title":["過沃素酸によるキシランの酸化について"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-06-21T07:56:34.882393+00:00"}